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61.
强水动力湖泊夏季分层期氮的生物地球化学循环初步研究:以贵州红枫湖南湖为例 总被引:9,自引:1,他引:9
湖泊在夏季由于藻类生长而消耗大量硝酸盐,水体硝酸盐含量一般要低于春季。而红枫湖南湖水体硝酸盐含量却高于春季(比平均含量高0.83mg/L),说明尚有其他重要的硝酸盐来源。据估算,南湖水体硝酸盐含量升高0.83mg/L约需要1.66×105kg硝酸盐,另外有约10.1×105kg硝酸盐随下泻水输出南湖,再加上夏季藻类生长(生产的chla量约为640kg)所消耗的硝酸盐3.52×105kg,共消耗硝酸盐15.28×105kg。扣除河流输入的4.42×105kg硝酸盐,南湖尚存在约10.86×105kg硝酸盐的亏空。利用氮稳定同位素示踪技术,结合硝酸盐及叶绿素a(chla)含量、溶解氧(DO)等的变化,认为这部分硝酸盐来自湖泊中下部(斜温层)有机质的大量矿化(硝化),是水动力驱动高DO的上部水体下沉从而引起下部有机质(硝化)的结果。南湖这种强水动力湖泊整个夏季分层期氮的生物地球化学循环是斜温层有机质矿化(硝化)释放硝酸盐和变温层藻类生长同化硝酸盐为有机质同时发生的特殊类型。 相似文献
62.
Natural riparian forest wetlands are known to be effective in their ability to remove nitrate by denitrification and sediments with attached phosphorus via sedimentation. On the other hand, litter input and decomposition is a process of crucial importance in cycling of nitrogen and phosphorus in a forest ecosystem.In this study we investigated the amount of nitrogen and phosphorus entering the alder fen ecosystem through leaf litter and its decomposition and the removal capacity of nitrogen and phosphorus by measuring denitrification and sedimentation in the alder fen.We found an average input of leaf litter during fall 1998 of 226 g m−2 yr−1 DW with nutrient concentration of 0.17% P and 1.6% N. This means a yearly input of 0.4 g m−2 yr−1 P and 3.6 g m−2 yr−1 N. The decomposition of leaf litter using litter bags with small and large mesh size resulted in bags with macroinvertebrates (large mesh size) and without macroinvertebrates (small mesh size). After 57 days the litter bags with macroinvertebrates had a decomposition rate of 79%.Denitrification was measured in May and June of 1997 using the acetylene inhibition technique on intact soil cores and slurry-experiments. The average annual denitrification rate was 0.2 g m−2 yr−1 N using data from the core experiments. The denitrification rate was higher after addition of nitrate, indicating that denitrification in the riparian alder fen is mainly controlled by nitrate supply.The sedimentation rate in the investigated alder fen ranged from 0.47 kg m−2 yr−1 DW to 4.46 kg m−2 yr−1 DW in 1998 depending on the study site and method we used. Sedimentation rates were lower in newly designed plate traps than in cylinder traps. The alder fen also showed lower rates than the adjacent creek Briese. Average phosphorus removal rate was 0.33 g m−2 yr−1 P.Input sources for the surface water of the alder fen are sediment mineralization and decomposition of leaf litter; output sources are sedimentation and denitrification. This study showed that a nutrient input of 24.58 kg ha−1 yr−1 N, 8.8 kg ha−1 yr−1 P and 419 kg ha−1 yr−1 DOC into the surface water of the alder fen is possible. Alder fens cannot improve water quality of an adjacent river system. This is only true for a nearly pristine alder fen with the hydrology of 10 months flooded conditions and 2 months non-flooding conditions a year. 相似文献
63.
西苕溪流域不同土地类型下氮元素输移过程 总被引:60,自引:3,他引:60
以西苕溪流域为研究对象,选择最有代表性的5种土地类型,模拟天然大暴雨,通过3次重复实验研究不同形态氮素随暴雨径流及径流沉积物的迁移过程,估算氮素在流域内不同土地利用/土地覆被条件下的损失率。研究结果表明,在相同的降雨条件下,氮素的流失速率和流失量随土地利用/土地覆被类型的不同表现出明显差异,地表径流水相总氮的流失量桑林最大,水田最小。水相不同形态的氮素流失量亦有所不同,悬浮颗粒态氮占地表径流水相总氮的70 %~90 %,水相溶解态氮的流失量以松林为最高,竹林、桑林和水田接近而且较低,不同类型的水相溶解态氮也随土地利用类型的不同表现出各自的特征。各土地类型单位面积、表层10 cm土壤氮素流失高达4.66~9.40 g·m-2,其中随径流沉积物相迁移的氮素占绝大部分(90 % 以上)。估算出的各土地利用类型总氮流失速率,地表径流水相为2.68~14.48 mg·m-2·min-1,径流沉积物相高达100.01~172.67 mg·m-2·min-1。 相似文献
64.
Gerrit de Leeuw Lucinda Spokes Tim Jickells Carsten Ambelas Skjth Ole Hertel Elisabetta Vignati Susanne Tamm Michael Schulz Lise-Lotte Srensen Britta Pedersen Laura Klein K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743
The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m−2 day−1, which has the potential to promote primary productivity of 5.3 mmol C m−2 day−1. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km−1, i.e. 0.19 mmol N m−2 day−1 which has the potential to promote primary productivity of 1.2 mmol C m−2 day−1. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NOx and NH3 are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m−2 day−1, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m2 is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem. 相似文献
65.
66.
Laser microprobe for the study of noble gases and nitrogen in single grains: A case study of individual chondrules from the Dhajala meteorite 总被引:1,自引:0,他引:1
A laser microprobe capable of analysing nitrogen and noble gases in individual grains with masses less than a milligram is
described. It can be used in both continuous wave (CW) mode, useful for stepwise heating of an individual grain, as well as
in pulsed mode, useful for ablating material from a small selected area of a sample, for gas extraction. We could achieve
low blanks (in ccSTP units) for 4He(4.8 x 10{-12}),22Ne(1.0 x 10{-12}),36Ar(1.0 x10
-13),84Kr(2.9 x 10{-14}),132 Xe(2.6 x 10{-14}), and N (87 pg), using this system. Preliminary data for individual chondrules from the Dhajala meteorite show that noble
gases and nitrogen from grains as small as 170 microgram can be analysed using the present laser microprobe setup. The amount
of trapped neon in Dhajala chondrules is very small, and nitrogen in the chondrules is isotopically heavier as compared to
the bulk meteorite. 相似文献
67.
The rate of the reversible homogeneous disproportionation of polysulfides was studied by following the optical absorbance of polysulfide solutions in a continuous plug flow reactor equipped with an on-line photometric detector. In order to avoid heterogeneous slow reactions involving sulfur colloids or precipitate, the reaction was initiated by an abrupt pH change from an undersaturated solution containing predominantly tetrasulfide species to a pH where pentasulfide is the dominant species. The disproportionation was found to follow first order reversible reaction dynamics. At environmentally relevant conditions the characteristic time of the disproportionation reaction is of the order of 10 s. This characteristic time implies that necessary conditions for speciation of the different polysulfide species by chromatography or another separation and subsequent quantification scheme should be of the order of 1 s. 相似文献
68.
利用光谱反射率估算叶片生化组分和籽粒品质指标研究 总被引:2,自引:0,他引:2
对可见光至短波红外波段(350—2500nm)冬小麦田间冠层光谱反射率与叶片含氮量间的关系进行了相关分析。结果表明,820—1100nm波段的光谱反射率与叶片含氮量极显著正相关;1150—1300hm波段的光谱反射率与叶片含氮量显著正相关,以上两波段为叶片全氮的敏感波段。对各生育时期叶片全氮与其他生化组分的关系进行了回归分析,并建立了相关的回归方程,显著性检验结果表明,方程具有较高的可靠性。小麦的叶片含氮量可以估算其它生化组分及干物质指标含量,开花期叶片含氮量可用来估测籽粒蛋白质和干面筋等品质指标含量。 相似文献
69.
S. Solberg T. Krognes F. Stordal OØ Hov H. J. Beine D. A. Jaffe K. C. Clemitshaw S. A. Penkett 《Journal of Atmospheric Chemistry》1997,28(1-3):209-225
Simultaneousindependent measurements of NOy and NOx(NOx= NO + NO2) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NOxmixing ratio was 27 pptv and did not show any cyclethrough the period. The NOy mixing ratio showeda maximum in late March, while the difference betweenNOy and PAN decreased during spring. This is anindication of the dominance of PAN in the NOybudget in the Arctic, but possible changes in theefficiency of the NOy converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1. 相似文献
70.
氮同位素比(^15N/^14N)在地下水氮污染研究中的应用基础 总被引:25,自引:1,他引:25
华北地下水中硝态氮浓度和δ^15N值如下:在自然状态下为4.4≤+5,来自下水道粪便污染者为20-70和+10-+20,受化肥污染者为30-60和-2-+5。因此,氮同位素可用来识别氮污染来源和氮的迁移。 相似文献